Notes on carbon dating
group published the list of tests to be performed on the shroud; these aimed to identify how the image was impressed onto the cloth, to verify the relic's purported origin, and to identify better-suited conservation methods. We are faced with actual blackmail: unless we accept the conditions imposed by the laboratories, they will start a marketing campaign of accusations against the Church, which they will portray as scared of the truth and enemy of science.
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As a result it is always undergoing natural radioactive decay while the abundances of the other isotopes are unchanged.
Carbon-14 is most abundant in atmospheric carbon dioxide because it is constantly being produced by collisions between nitrogen atoms and cosmic rays at the upper limits of the atmosphere.